Was busy (life...) before I finally got to work on this. Sharing the 2 approaches to recover files, I tried for afterworld.
1.) Mount ZFS pool via historic transaction groups (TGX) in order to access a previous state of the pool still available in the records. Here is a link outlining this a bit:
https://lists.freebsd.org/pipermail/freebsd-hackers/2013-July/043131.html
In my case it failed because I changed the SSD cache a few days before I deleted my stuff so most historic TGX didn´t mount because they lacked the old cache device.
2.) UFS Explorer. This software - e.g. from a Linux thumbdrive or even from Windows - can scan the whole pool block for block and restore deleted files - in my case even from a RAIDZ2!
Took several days and I accidentially ran the scan with the professional version for which there is no hobbyist licence. Should have used the RAID version instead, but now I was unable to just export my large files.
But as the trial allows to export files smaller than a certain size, I was able to mount the recovered Virtualbox images and export the missing configs from their folder tree - which I could combine with older backups of my VirtualBox images.
I cannot confirm that the whole 4GB disk image would have been restored without a fault, but all the files I exported from there where uncorrupted. Great software and worth a tr(y/ial) in case of anyone repeating my stupidity.
Thanks to everyone commenting!
P.S. Even more stupid after learning, how easy ZFS snapshots can be used and cron scripted!