Setting it up as a basic firewall is about as simple as it gets. Just assign your WAN, and LAN interface if you're going to have one, when you're installing it and it does the rest. You need one network card for each interface, with a minimum of one for the WAN interface.
Administration is done through the web GUI. Change your Admin password through the Setup Wizard in the System section of the dropdown menu right away, then go through the General Setup and Advanced sections too.
Making rules is also done through the web GUI. I just use it on my home network and don't use ssh so am unable to guide you though that part, but you should be able to figure out what ports you're going to be using and make the rules that apply.
There are a number of different packages you can install though the System section. The only one I use is pfBlocker so I can block all incoming and outgoing traffic to different countries by default.
Take it one step at a time. If you run into any problems the people at the pfSense forums are pretty quick to offer help.