If, by any chance, you mean that your MBR is broken, and not your BIOS you can try the following:
I'm not sure what options you can have by booting PCBSD, but I assume that you'll be able to run an emergency/fixit console somehow (if not, boot with some FreeBSD-9 disk1). If so, you should give the following command as root:
# fdisk -B -b /boot/boot0 [i]yourbootdevice[/i]
yourbootdevice should be replaced by the name of your disk, which is usually something like /dev/ad0 or /dev/da0. To be sure, you can run:
$ dmesg | less
and see what is written with respect to your disk.
Good luck.