Having trouble using wine (Undefined symbol "__pw_scan@FBSDprivate_1.0")

Does /usr/lib32/libthr.so.3 exist? Does /var/run/ld-elf32.so.hints exist (and contain /usr/lib32)?
You could try running ldconfig -32 (if the lib is there).
 
Oh, you extracted the contents of lib32.txz in /usr/lib32. Extraction should be done from / (the archive contains the directory usr/lib32/).

tar -C / -zxf lib32.txz should do the right thing.
 
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